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Electrochemical Sensors in Bioanalysis
by Raluca-Ioana Stefan"Covers the most recent methods and materials for the construction, validation, analysis, and design of electrochemical sensors for bioanalytical, clinical, and pharmaceutical applications--emphasizing the latest classes of enantioselective electrochemical sensors as well as electrochemical sensors for in vivo and in vitro diagnosis, for DNA assay
Electrochemical Supercapacitors for Energy Storage and Delivery: Fundamentals and Applications (Electrochemical Energy Storage and Conversion #1)
by Jiujun Zhang Aiping Yu Victor ChabotAlthough recognized as an important component of all energy storage and conversion technologies, electrochemical supercapacitators (ES) still face development challenges in order to reach their full potential. A thorough examination of development in the technology during the past decade, Electrochemical Supercapacitors for Energy Storage and Delivery: Fundamentals and Applications provides a comprehensive introduction to the ES from technical and practical aspects and crystallization of the technology, detailing the basics of ES as well as its components and characterization techniques. The book illuminates the practical aspects of understanding and applying the technology within the industry and provides sufficient technical detail of newer materials being developed by experts in the field which may surface in the future. The book discusses the technical challenges and the practical limitations and their associated parameters in ES technology. It also covers the structure and options for device packaging and materials choices such as electrode materials, electrolyte, current collector, and sealants based on comparison of available data. Supplying an in depth understanding of the components, design, and characterization of electrochemical supercapacitors, the book has wide-ranging appeal to industry experts and those new to the field. It can be used as a reference to apply to current work and a resource to foster ideas for new devices that will further the technology as it becomes a larger part of main stream energy storage.
Electrochemical Systems (The ECS Series of Texts and Monographs)
by John Newman Nitash P. BalsaraProvides a comprehensive understanding of a wide range of systems and topics in electrochemistry This book offers complete coverage of electrochemical theories as they pertain to the understanding of electrochemical systems. It describes the foundations of thermodynamics, chemical kinetics, and transport phenomena—including the electrical potential and charged species. It also shows how to apply electrochemical principles to systems analysis and mathematical modeling. Using these tools, the reader will be able to model mathematically any system of interest and realize quantitative descriptions of the processes involved. This brand new edition of Electrochemical Systems updates all chapters while adding content on lithium battery electrolyte characterization and polymer electrolytes. It also includes a new chapter on impedance spectroscopy. Presented in 4 sections, the book covers: Thermodynamics of Electrochemical Cells, Electrode Kinetics and Other Interfacial Phenomena, Transport Processes in Electrolytic Solutions, and Current Distribution and Mass Transfer in Electrochemical Systems. It also features three appendixes containing information on: Partial Molar Volumes, Vectors and Tensors, and Numerical Solution of Coupled, Ordinary Differential Equations. Details fundamental knowledge with a thorough methodology Thoroughly updated throughout with new material on topics including lithium battery electrolyte characterization, impedance analysis, and polymer electrolytes Includes a discussion of equilibration of a charged polymer material and an electrolytic solution (the Donnan equilibrium) A peerless classic on electrochemical engineering Electrochemical Systems, Fourth Edition is an excellent resource for students, scientists, and researchers involved in electrochemical engineering.
Electrochemical Systems
by John Newman Karen E. Thomas-AlyeaThe new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and expanded, the Third Edition covers important new treatments, ideas, and technologies while also increasing the book's accessibility for readers in related fields. Rigorous and complete presentation of the fundamental concepts In-depth examples applying the concepts to real-life design problems Homework problems ranging from the reinforcing to the highly thought-provoking Extensive bibliography giving both the historical development of the field and references for the practicing electrochemist.
Electrochemical Techniques in Corrosion Science and Engineering (Corrosion Technology Ser. #Vol. 18)
by Rudolph G. Buchheit Robert G. Kelly John R. Scully David ShoesmithThis book describes the origin, use, and limitations of electrochemical phase diagrams, testing schemes for active, passive, and localized corrosion, the development and electrochemical characterization of passivity, and methods in process alteration, failure prediction, and materials selection. It offers useful guidelines for assessing the efficac
Electrochemical Transformation of Renewable Compounds
by Zhiqun Lin Xueqin Liu Zhen Li Yanqiu HuangElectrochemical conversion process can be used to generate power, store energy and synthesize chemicals, which plays a key role in the development of sustainable energy resources. Electrochemical Transformation of Renewable Compounds presents the basic fundamentals of different electrochemical transformations for clean energy and places significant emphasis on the key developments of various electrochemical processes using state-of-the-art materials. Written by electrochemical energy scientists who have worked on the application of electrocatalysis in the environmental and energy area, this book provides comprehensive coverage of main electrochemical transformation processes, including oxygen evolution, hydrogen generation, oxygen reduction, carbon dioxide reduction, nitrogen reduction, methanol oxidation, urea oxidation and ammonia oxidation.
Electrochemical Water Electrolysis: Fundamentals and Technologies (Electrochemical Energy Storage and Conversion)
by Lei Zhang Jiujun Zhang Xueliang Sun David P. Wilkinson Hongbin ZhaoThis book comprehensively describes the fundamentals of electrochemical water electrolysis as well as the latest materials and technological developments. It addresses a variety of topics such as electrochemical processes, materials, components, assembly and manufacturing, and degradation mechanisms, as well as challenges and strategies. It also includes an understanding of how materials and technologies for electrochemical water electrolysis have developed in recent years, and it describes the progress in improving performance and providing benefits to energy systems and applications. Features the most recent advances in electrochemical water electrolysis to produce hydrogen Discusses cutting-edge materials and technologies for electrochemical water electrolysis Includes both experimental and theoretical approaches that can be used to guide and promote materials as well as technological development for electrochemical water electrolysis Comprises work from international leading scientists active in electrochemical energy and environmental research and development Provides invaluable information that will benefit readers from both academia and industry With contributions from researchers at the top of their fields, the book includes in-depth discussions covering the engineering of components and applied devices, making this an essential read for scientists and engineers working in the development of electrochemical energy devices and related disciplines.
Electrochemical Water Splitting: Fundamentals, Challenges and Advances (Materials Horizons: From Nature to Nanomaterials)
by Yousef Haik Tanveer ul HaqThis book provides a comprehensive platform for the research, scientific and educational communities working on electrocatalysis. It covers water electrolysis from different fields of catalysis research, deals with the fundamentals and critically discusses the precise and correct use of evaluating parameters and their calculation for a fair evaluation. Readers find an analysis to probe the origin of different bottlenecks in water electrolysis and scientific methods to enhance the electrode selectivity with high intrinsic activity, effective mass and electron transfer ability, abundant active sites with super hydrophilicity-aerophobicity characteristics and structural, mechanical and chemical stability with high corrosion resistance.
Electrochemically Assisted Remediation of Contaminated Soils: Fundamentals, Technologies, Combined Processes and Pre-Pilot and Scale-Up Applications (Environmental Pollution #30)
by M. A. Rodrigo E. V. Dos SantosThis book provides an overview of the current development status of remediation technologies involving electrochemical processes, which are used to clean up soils that are contaminated with different types of contaminants (organics, inorganics, metalloids and radioactive). Written by internationally recognized experts, it comprises 21 chapters describing the characteristics and theoretical foundations of various electrochemical applications of soil remediation. The book’s opening section discusses the fundamental properties and characteristics of the soil, which are essential to understand the processes that can most effectively remove organic and inorganic compounds. This part also focuses on the primary processes that contribute to the application of electrochemically assisted remediation, hydrodynamic aspects and kinetics of contaminants in the soil. It also reviews the techniques that have been developed for the treatment of contaminated soils using electrochemistry, and discusses different strategies used to enhance performance, the type of electrode and electrolyte, and the most important operating conditions. In turn, the book’s second part deals with practical applications of technologies related to the separation of pollutants from soil. Special emphasis is given to the characteristics of these technologies regarding transport of the contaminants and soil toxicity after treatment. The third part is dedicated to new technologies, including electrokinetic remediation and hybrid approaches, for the treatment of emerging contaminants by ex-situ and in-situ production of strong oxidant species used for soil remediation. It also discusses pre-pilot scale for soil treatment and the use of solar photovoltaic panels as an energy source for powering electrochemical systems, which can reduce both the investment and maintenance costs of electrochemically assisted processes.
Electrochemically Enabled Sustainability: Devices, Materials and Mechanisms for Energy Conversion
by Kwong-Yu Chan Chi-Ying Vanessa LiWith contributions from leading researchers in their fields, this book provides an overview of the most important electrochemical power sources in development today. Focusing on materials, design, and performance, the text presents the most recent and innovative technologies employed in battery and fuel cell technologies. Topics include acid-alkaline batteries, microbial fuel cells, lithium batteries, lead acid batteries, ultracapacitors, vanadium flow batteries, and carbon dioxide electroreduction. The book discusses the advantages of these cells over conventional methodologies, and their future applications.
Electrochemistry and Corrosion Science
by Nestor PerezThe second edition of this textbook includes refined text in each chapter, new sections on corrosion of steel-reinforced concrete and on cathodic protection of steel reinforced bars embedded in concrete, and some new solved examples. The book introduces mathematical and engineering approximation schemes for describing the thermodynamics and kinetics of electrochemical systems, which are the essence of corrosion science, in addition to electrochemical corrosion, forms of corrosion and mechanisms of corrosion. This approach should capture the reader's attention on the complexity of corrosion. Thus, the principles of electrochemistry and electrochemical cells are subsequently characterized in simple electrolytes from a thermodynamics point of view.
Electrochemistry at the Nanoscale
by Patrik Schmuki Sannakaisa VirtanenFor centuries, electrochemistry has played a key role in technologically important areas such as electroplating or corrosion. In recent decades, electrochemical methods are receiving increasing attention in important strongly growing fields of science and technology such as nanosciences (nanoelectrochemistry) and life-sciences (organic and biological electrochemistry). Characterization, modification and understanding of various electrochemical interfaces or electrochemical processes at the nanoscale, has led to a huge increase of the scientific interest in electrochemical mechanisms as well as of application of electrochemical methods in novel technologies. This book presents exciting emerging scientific and technological aspects of the introduction of the nanodimension in electrochemical approaches are presented in 12 chapters/subchapters.
Electrochemistry Crash Course for Engineers
by Slobodan PetrovicThis book is a concise introductory guide to understanding the foundations of electrochemistry. By using simplified classroom-tested methods developed while teaching the subject to engineering students, the author explains in simple language an otherwise complex subject that can be difficult to master for most. It provides readers with an understanding of important electrochemical processes and practical industrial applications, such as electrolysis processes, metal electrowinning, corrosion and analytical applications, and galvanic cells such as batteries, fuel cells, and supercapacitors. This powerful tutorial is a great resource for students, engineers, technicians, and other busy professionals who need to quickly acquire a solid understanding of the science of electrochemistry.
Electrochemistry for Cultural Heritage (Monographs in Electrochemistry)
by Antonio Doménech-Carbó María Teresa Doménech-CarbóThis monograph overviews the importance of electrochemistry in the field of cultural heritage, including archaeology, conservation and restoration topics. The application of electrochemical techniques in these domains have experienced a notable growth during the last ten years, in particular with regards to the elucidation of composition, manufacturing techniques and chronology of archaeological artefacts. This book describes the application of solid state electrochemistry techniques for the use of samples at the nanogram level from paintings, metallic, ceramic, glass, glazed, wooden, and other objects, and it also includes the description of new dating procedures for archaeological objects made of these materials. It is a valuable contribution to the field of cultural heritage and will be of great interest to archaeologists, conservators and restorers as well as to physicists and chemists working on the scientific examination of works of art.
Electrochemistry for the Environment
by Christos Comninellis Guohua ChenThe book starts with the fundamentals of environmental electrochemistry, introducing the basic techniques in selecting and fabricating electrode materials, followed by a theoretical analysis of the electrochemical processes, green electrochemical operation, discussion of electrochemical technologies in water treatment, and then examination of the established wastewater treatment technologies such as electrochemical reactors for metal recovery, electrocoagulation, electroflotation and electrooxidation. Emerging technologies such as electrophotooxidation, electro disinfection, and electrochemical technologies in sludge and soil treatment will also be analyzed. This book will be an excellent reference for young researchers starting new research programs and also for industrialists who wish to appreciate the technologies.
Electrochemistry in Ionic Liquids
by Angel A. J. TorrieroThis is a set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids - as opposed to the more commonly used aqueous and organic environments - and the many applications. Readers will find 20 chapters gathered in two books : Electrochemistry in Ionic Liquids - Volume 1, Fundamentals: This book critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed. Electrochemistry in Ionic Liquids - Volume 2, Applications: The major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.
Electrochemistry of Carbon Electrodes
by Richard C. Alkire Jacek Lipkowski Philip N. BartlettThe book sets the standard on carbon materials for electrode design. For the first time, the leading experts in this field summarize the preparation techniques and specific characteristics together with established and potential applications of the different types of carbon-based electrodes. An introductory chapter on the properties of carbon together with chapters on the electrochemical characteristics and properties of the different modifications of carbon such as carbon nanotubes, graphene, carbon fiber, diamond or highly ordered pyrolytic graphite provide the reader with the basics on this fascinating and ubiquitous electrode material. Cutting-edge technologies such as carbon electrodes in efficient supercapacitors, Li-ion batteries and fuel cells, or electrodes prepared by screen-printing are discussed, giving a complete but concise overview about the topic. The clearly structured book helps newcomers to grasp easily the principles of carbon-based electrodes, while researchers in fundamental and applied electrochemistry will find new ideas for further research on related key technologies.
Electrochemistry of Immobilized Particles and Droplets
by Fritz Scholz Uwe Schröder Rubin Gulaboski Antonio Doménech-CarbóThis second edition of a successful and highly-accessed monograph has been extended by more than 100 pages. It includes an enlarged coverage of applications for materials characterization and analysis. Also a more detailed description of strategies for determining free energies of ion transfer between miscible liquids is provided. This is now possible with a "third-phase strategy" which the authors explain from theoretical and practical points of view. The book is still the only one detailing strategies for solid state electroanalysis. It also features the specific potential of the techniques to use immobilized particles (for studies of solid materials) and of immobilized droplets of immiscible liquids for the purpose of studying the three-phase electrochemistry of these liquids. This also includes studies of ion transfer between aqueous and immiscible non-aqueous liquids. The bibliography of all published papers in this field of research has been expanded from 318 to now 444 references in this second edition. Not only are pertinent references provided at the end of each chapter, but the complete list of the cited literature is also offered as a separate chapter for easy reference.
Electrochemistry of Insertion Materials for Hydrogen and Lithium
by Joo-Young Go Su-Il Pyun Jong-Won Lee Heon-Cheol ShinThe understanding of hydrogen/lithium insertion phenomena is of great importance for the development of the next generation of functional electrochemical devices such as rechargeable batteries, electrochromic devices, and fuel cells. This volume introduces a variety of viable electrochemical methods to identify reaction mechanisms and evaluate relevant kinetic properties of insertion electrodes. The authors also outline various ways to analyze anomalous behaviour of hydrogen/lithium transport through insertion electrodes.
Electrochemistry of Metal Chalcogenides
by Mirtat BouroushianThe author provides a unified account of the electrochemical material science of metal chalcogenide (MCh) compounds and alloys with regard to their synthesis, processing and applications. Starting with the chemical fundamentals of the chalcogens and their major compounds, the initial part of the book includes a systematic description of the MCh solids on the basis of the Periodic Table in terms of their structures and key properties. This is followed by a general discussion on the electrochemistry of chalcogen species, and the principles underlying the electrochemical formation of inorganic compounds/alloys. The core of the book offers an insight into available experimental results and inferences regarding the electrochemical preparation and microstructural control of conventional and novel MCh structures. It also aims to survey their photoelectrochemistry, both from a material-oriented point of view and as connected to specific processes such as photocatalysis and solar energy conversion. Finally, the book illustrates the relevance of MCh materials to various applications of electrochemical interest such as (electro)catalysis in fuel cells, energy storage with intercalation electrodes, and ion sensing.
Electrochemistry of Metal Complexes
by Arvydas SurvilaA systematic analysis of electrochemical processes involving metal complexes. Starting with general considerations on equilibria in solutions and at interfaces as well as on mass transport, the text acquaints readers with the theory and common experimental practice for studying electrochemical reactions of metals complexes. The core part of the book deals with all important aspects of electroplating, including a systematic discussion of co-deposition of metals and formation of alloys. It also discusses such related subjects as oxide layer formation and hydrogen evolution as a side reaction.
Electrochemistry of N4 Macrocyclic Metal Complexes
by Fethi Bedioui Jose H. ZagalThisnew edition describes the state of the art regarding molecular catalysts suchas MN4 metal complexes, like porphyrins and phthalocyanines. This volumefocuses on the particular case of the electrocatalysis of the reduction of O2for practical applications in fuel cells and air batteries. Indeed, active andstable materials have been developed in the last 5 years where MN4 catalyticsystems can be obtained by the pyrolysis of starting materials that do notnecessarily involve MN4 complexes. These latter systems constitute a new classof stable and highly active non-precious metal catalysts for ORR that canreplace expensive Platinum containing electrodes. The book also offersfuture projections and points out new fields of research and developmentof these non-precious metal catalysts.
Electrochemistry of Porous Materials
by Antonio Doménech CarbóElectrochemistry of Porous Materials describes essential theoretical aspects of the electrochemistry of nanostructured materials and primary applications, incorporating the advances in the field in the last ten years including recent theoretical formulations and the incorporation of novel materials. Concentrating on nanostructured micro- and mesoporous materials, the highly anticipated Second Edition offers a more focused and practical analysis of key porous materials considered relatively homogeneous from an electrochemical point of view. The author details the use of electrochemical methods in materials science for characterization and their applications in the fields of analysis, energy production and storage, environmental remediation, and the biomedical arena. Additional features include: Incorporates new theoretical advances in the voltammetry of porous materials and multiphase porous electrochemistry. Includes new developments in sensing, energy production and storage, degradation of pollutants, desalination and drug release. Describes redox processes for different porous materials, assessing their electrochemical applications. Written at an accessible and understandable level for researchers and graduate students working in the field of material chemistry. Selective and streamlined, Electrochemistry of Porous Materials, Second Edition culls a wide range of relevant and practically useful material from the extensive literature on the subject, making it an invaluable reference for readers of all levels of understanding.
Electrochemistry of Technetium (Monographs in Electrochemistry)
by Maciej Chotkowski Andrzej CzerwińskiThis book provides detailed information on the electrochemistry of technetium compounds. After a brief physico-chemical characterization of this element, it presents the comparative chemistry of technetium, manganese and rhenium. Particular attention is paid to the stability, disproportionation, comproportionation, hydrolysis and polymerization reactions of technetium ions and their influence on the observed redox systems. The electrochemical properties of both inorganic as well as organic technetium species in aqueous and non-aqueous solutions are also discussed. The respective chapters cover the whole spectrum of topics related to the application of technetium in nuclear medicine, electrochemistry of technetium in spent nuclear fuel (including corrosion properties of technetium alloys), and detecting trace amounts of technetium with the aid of electrochemical methods. Providing readers with information not easily obtained in any other single source, the book will appeal to researchers working in nuclear chemistry, nuclear medicine or the nuclear industry.
Electrochemistry of Zirconia Gas Sensors
by Serge ZhuiykovThe first book to present a detailed analysis of the electrochemistry, development, modeling, optimization, testing, and technology behind modern zirconia-based sensors, Electrochemistry of Zirconia Gas Sensors explores how to tailor these sensors to meet specific industrial needs. The book addresses a range of different stages of development in zi