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Metal Toxicity in Plants: Perception, Signaling and Remediation

by Dharmendra K. Gupta Luisa M. Sandalio

Heavy metal accumulation in soil and water from natural sources or anthropogenic activities have produced severe environmental contamination in some parts of the world due to the persistence of metals in the environment by their accumulation throughout the food chain. The purpose of this book is to present the most recent advances in this field, mainly concerning the uptake and translocation of heavy metals in plants, mechanisms of toxicity, perception of metal and regulation of cell response under metal stress. Another key feature of this book is related to the studies on signaling and remediation processes in recent years, which have taken advantage of recent technological advances including "omic" approaches. In recent years transcriptomic, proteomic and metabolomic studies have become very important tools for analyzing both the dynamics of changes in gene expression and the profiles of protein and metabolites under heavy metal stress. This information is also very useful for plotting the complex signaling and metabolic network induced by heavy metals, in which hormones and reactive oxygen species (ROS) also play an important role. Understanding the mechanism involved in sequestration and hyperaccumulation is very important to developing new strategies of phytoremediation, which are reviewed in several chapters of this book. The information included yields very stimulating insights into the mechanism involved in the regulation of plant responses to heavy metals, which in turn improve our knowledge of cell regulation under metal stress and the use of plants for phytoremediation.

Metal Toxicology Handbook

by Debasis Bagchi and Manashi Bagchi

Heavy metals and metalloids, singly or in combination, induce toxic manifestations either through acute or chronic pathology. In particular, long-term chronic exposure to diverse heavy metals and metalloids to humans and animals can lead to numerous physical, muscular, neurological, nephrological, and diverse degenerative diseases and dysfunctions, including multiple sclerosis, muscular dystrophy, Parkinson’s and Alzheimer’s diseases, cardiovascular disorders, and several others. Recognized heavy metals such as lead, mercury, arsenic, cadmium, thallium, and hexavalent chromium are known for enormous toxicity. The immediate vital signs of acute heavy metal exposure include nausea, vomiting, diarrhea, and acute abdominal pain. Mercury has been identified as the most toxic heavy metal, and mercury poisoning is known as acrodynia or pink disease. Similarly, lead, another toxic heavy metal, was at one time an integral part of painting. Metal Toxicology Handbook further explains and discusses the varying attributes of metals, discussing toxicity, safety, and proper human utilization of metals. Beginning with a broad overview of metals, metalloids, redox biology, and neurodegeneration and going further into the roles, benefits, and toxicity of metals with each section, the text contains 28 chapters from eminent researchers and scientists in their respective fields and is a must-have for anyone researching the potential toxicity in metals. Key Features Discusses the pathology of metal toxicity Highlights the benefits of metals Explains the mechanism and salient features of restoring metabolic homeostasis Highlights dose-dependent beneficial and adverse effects of vanadium safety and toxicity The initial introductory section provides a broad overview of metals, metalloids, redox biology, and neurodegeneration. The second section discusses the pathology of metal toxicity in two chapters, while the third section highlights the mechanism and salient features of restoring metabolic homeostasis in two chapters. The fourth section demonstrates the aspect of radionuclides toxicity. In a change of pace, the fifth section discusses the benefits of metals in four chapters. The sixth section, titled "Toxic Manifestations by Diverse Heavy Metals and Metalloids," provides fourteen chapters that discuss the toxicological mechanism and manifestation of individual metals. The editors have crafted a commentary titled "A Treatise on Metal Toxicity" and summarized a vivid scenario of metal toxicity and its consequences.

Metal and Alloy Bonding - An Experimental Analysis

by M. Prema Rani R. Saravanan

Charge density analysis of materials provides a firm basis for the evaluation of the properties of materials. The design and engineering of a new combination of metals requires a firm knowledge of intermolecular features. Recent advances in technology and high-speed computation have made the crystal X-ray diffraction technique a unique tool for the determination of charge density distribution in molecular crystal. Methods have been developed to make experimental probes capable of unraveling the features of charge densities in the intra- and inter-molecular regions of crystal structures. In Metal and Alloy Bonding - An Experimental Analysis, the structural details of materials are elucidated with the X-ray diffraction technique. Analyses of the charge density and the local and average structure are given to reveal the structural properties of technologically important materials. Readers will gain a new understanding of the local and average structure of existing materials. The electron density, bonding, and charge transfer studies in Metal and Alloy Bonding - An Experimental Analysis contain useful information for researchers in the fields of physics, chemistry, materials science, and metallurgy. The properties described in these studies can contribute to the successful engineering of these technologically important materials.

Metal and Bone Drilling - The Thermal Aspects

by Rui Li Albert J. Shih Bruce L. Tai

This book introduces state-of-the-art experimental and numerical methods and examples for evaluating the drilling performance of engineering and biological materials, particularly in thermal aspects. The authors use a common pathway to present the technological and analytical methods for both industry (metal) drilling and orthopaedic surgery (bone) drilling research, making this book a resource for both industrial and clinical readers who wish to understand the evolution of technologies, techniques and challenges in drilling. The authors also focus on advanced engineering materials, such as titanium alloys and high-strength cast irons, which have broad applications in the automotive, aerospace, medical device and sports industries. This book is a must-read for a broad audience, including engineering students in upper-level undergraduate and graduate courses that involve machining processes; for surgery residents, fellows, and practicing surgeons; and for engineers in the medical device industry who develop new bone cutting tools.Bridges the knowledge on drilling from the manufacturing industry to healthcare;Covers the experimental and modeling aspects of drilling thermal analysis;Includes experimental studies that contain parameters and data that emulate practical production and clinical drilling.

Metal and Ceramic Matrix Composites (Series in Materials Science and Engineering)

by Brian Cantor Fionn Dunne Ian Stone

With contributions from leading experts in their respective fields, Metal and Ceramic Matrix Composites provides a comprehensive overview of topics on specific materials and trends. It is a subject regularly included as a final year option in materials science courses and is also of much industrial and academic interest. The book begins wit

Metal and Metal Oxides for Energy and Electronics (Environmental Chemistry for a Sustainable World #55)

by Eric Lichtfouse Saravanan Rajendran Francisco Gracia Jiaqian Qin

Energy is a key world issue in the context of climate change and increasing population, 'calling for alternative fuels, better energy storage, and energy-saving devices. This books reviews the principles and applications of metals and metal oxides for energy, with focus on batteries, electrodes, nanomaterials, electronics, supercapacitors, biofuels and sensors.

Metal and Metal-Oxide Based Nanomaterials: Synthesis, Agricultural, Biomedical and Environmental Interventions (Smart Nanomaterials Technology)

by Azamal Husen Rakesh Kumar Bachheti Archana Bachheti

The book in hand, namely “Metal and Metal-Oxide Based Nanomaterials (Synthesis, Agricultural, Biomedical and Environmental Interventions”, focuses on the synthesis methods, characterization techniques, and diverse interventions utilizing these nanomaterials in the fields of agriculture, biomedicine, and environmental remediation. The specific applications discussed include food packaging, post-harvest disease management, crop production, drug delivery systems, other biomedical applications, photocatalytic degradation of environmental pollutants, and wastewater treatment. Additionally, it also addresses the potential risks associated with zinc nanoparticles in aquatic ecosystems and emphasizes the importance of further research and regulation in this field. Overall, the book provides valuable insights and serves as a comprehensive resource for researchers and scientists across various interdisciplinary subjects. It serves as a valuable resource for scientists, researchers, and students in nanotechnology, nanomedicine, environmental science, plant science, agriculture, chemistry, biotechnology, pharmacognosy, pharmaceuticals, industrial chemistry, and other interdisciplinary subjects. Moreover, this also inspires further research, innovation, and the development of sustainable solutions for a better future.

Metal, Metal Oxides and Metal Sulphides for Biomedical Applications (Environmental Chemistry for a Sustainable World #58)

by Eric Lichtfouse Mu. Naushad Saravanan Rajendran D. Durgalakshmi

This book presents recent advances in inorganic nanomaterials for healthcare, with focus on the synthesis, medical applications and toxicity of metals, metal oxides and metal sulfides. Major applications include diagnosis, bioimaging, biosensing, healing and therapy in cancer, diabetes, cardiovascular diseases, obesity, metabolic syndrome, dentistry and antimicrobials.

Metal, Metal-Oxides and Metal Sulfides for Batteries, Fuel Cells, Solar Cells, Photocatalysis and Health Sensors (Environmental Chemistry for a Sustainable World #62)

by Eric Lichtfouse Saravanan Rajendran Jiaqian Qin Hassan Karimi-Maleh

This book summarizes recent findings on the use of new nanostructured materials for biofuels, batteries, fuel cells, solar cells, supercapacitors and health biosensors. Chapters describe principles and how to choose a nanomaterial for specific applications in energy, environment and medicine.

Metal-Air Batteries: Fundamentals and Applications

by Xin-Bo Zhang

A comprehensive overview of the research developments in the burgeoning field of metal-air batteries An innovation in battery science and technology is necessary to build better power sources for our modern lifestyle needs. One of the main fields being explored for the possible breakthrough is the development of metal-air batteries. Metal-Air Batteries: Fundamentals and Applications offers a systematic summary of the fundamentals of the technology and explores the most recent advances in the applications of metal-air batteries. Comprehensive in scope, the text explains the basics in electrochemical batteries and introduces various species of metal-air batteries. The author-a noted expert in the field-explores the development of metal-air batteries in the order of Li-air battery, sodium-air battery, zinc-air battery and Mg-O2 battery, with the focus on the Li-air battery. The text also addresses topics such as metallic anode, discharge products, parasitic reactions, electrocatalysts, mediator, and X-ray diffraction study in Li-air battery. Metal-Air Batteries provides a summary of future perspectives in the field of the metal-air batteries. This important resource: -Covers various species of metal-air batteries and their components as well as system designation -Contains groundbreaking content that reviews recent advances in the field of metal-air batteries -Focuses on the battery systems which have the greatest potential for renewable energy storage Written for electrochemists, physical chemists, materials scientists, professionals in the electrotechnical industry, engineers in power technology, Metal-Air Batteries offers a review of the fundamentals and the most recent developments in the area of metal-air batteries.

Metal-Air Batteries: Principles, Progress, and Perspectives

by Ram K. Gupta

Metal-Air Batteries: Principles, Progress, and Perspectives covers the entire spectrum of metal-air batteries, their working principles, recent advancement, and future perspectives. Leading international researchers address materials design, electrochemistry, and architectural aspects. The fundamentals of metal-air materials for cathode and anode, their synthetic approaches, chemistries to modify their properties to provide high energy and power densities, along with long life and stable electrochemical characteristics are detailed. Key Features: Covers materials, chemistry, and technologies for metal-air batteries. Reviews state-of-the-art progress and challenges in metal-air batteries Provides fundamentals of the electrochemical behavior of various metal-air batteries. Offers insight into tuning the properties of materials to make them suitable for metal-air batteries. Provides new direction and a better understanding to scientists, researchers, and students working in diverse fields. This is a unique offering and a valuable resource for a wide range of readers including those in academia and industries worldwide.

Metal-Air and Metal-Sulfur Batteries: Fundamentals and Applications (Electrochemical Energy Storage and Conversion)

by Vladimir Neburchilov and Jiujun Zhang

Metal–air and metal–sulfur batteries (MABs/MSBs) represent one of the most efficient-energy storage technologies, with high round trip efficiency, a long life cycle, fast response at peak demand/supply of electricity, and decreased weight due to the use of atmospheric oxygen as one of the main reactants. This book presents an overview of the main MABs/MSBs from fundamentals to applications. Recent technological trends in their development are reviewed. It also offers a detailed analysis of these batteries at the material, component, and system levels, allowing the reader to evaluate the different approaches of their integration. The book provides a systematic overview of the components, design, and integration, and discusses current technologies, achievements, and challenges, as well as future directions. Each chapter focuses on a particular battery type including zinc–air batteries, lithium–air batteries, aluminum–air batteries, magnesium–air batteries, lithium–sulfur batteries, and vanadium–air redox flow batteries, and metal–sulfur batteries. Features the most recent advances made in metal–air/metal–sulfur batteries. Describes cutting-edge materials and technology for metal–air/metal–sulfur batteries. Includes both fundamentals and applications, which can be used to guide and promote materials as well as technology development for metal–air/metal–sulfur batteries. Provides a systematic overview of the components, design, and integration, and discusses current technologies, achievements, and challenges, as well as future directions. Covers a variety of battery types in depth, such as zinc–air batteries, lithium–air batteries, aluminum–air batteries, magnesium–air batteries, lithium–sulfur batteries, vanadium–air redox flow batteries, and metal–sulfur batteries.

Metal-Based Composite Nanomaterials

by Jun Yang Hui Liu

This book introduces the latest research developments in composite nanomaterials and summarizes the fundamentals and technical approaches in synthesis, fabrication and processing of composite nanomaterials. The author describes the intrinsic relationship between the catalytic properties and the physical and chemical effects in the composite materials, providing for theoretical and technical bases for effectively developing novel electrocatalyst - applications of the nanocomposites in energy conversion areas.

Metal-Catalyzed Polymerization: Fundamentals to Applications

by Samir H. Chikkali, Ashootosh V. Ambade, Bas de Bruin and Michael Shaver

The proposed book focusses on metal mediated/catalyzed “controlled/living radical polymerization” (CRP/LRP) methods. It surveys a wide variety of catalyzed polymerization reactions, making it essentially a “one stop” review in the field. A significant contribution to polymer science is “metathesis polymerization” discovered by Grubbs and others. The book will cover various metathesis polymerization methods and implications in polymer industry.

Metal-Catalyzed Reactions in Water

by Victorio Cadierno Pierre Dixneuf

Water is abundant in nature, non-toxic, non-flammable and renewable and could therefore be safer and economical for the chemical industrywherever it is used as a solvent. This book provides a comprehensive overview of developments in the use of water as a solvent for metalcatalysis, illustrating the enormous potential of water in developing new catalytic transformations for fi ne chemicals and molecular materialssynthesis. A group of international experts cover the most important metalcatalyzed reactions in water and bring together cutting-edge resultsfrom recent literature with the first-hand knowledge gained by the chapter authors. This is a must-have book for scientists in academiaand industry involved in the fi eld of catalysis, greener organic synthetic methods, water soluble ligands and catalyst design, as well as for teachers and students interested in innovative and sustainable chemistry.

Metal-Containing Molecules and Nanomaterials: From Diagnosis to Therapy (ISSN)

by Astrid Sigel Helmut Sigel Eva Freisinger Bettencourt-Dias, Ana de Sigel, Roland K. O.

Since the discovery and successful deployment of salvarsan to treat syphilis, as well as cisplatin as a cancer drug, the field of metallodrugs has been flourishing. In addition to therapeutic applications, metals and metal-containing molecules have properties, such as an electrochemical or an optical signal, that can be used to diagnose biologically relevant molecules or unravel cellular metabolism. Moreover, metals are part of the essential elements for life, and of increased attention in nutraceuticals. Most of the current diagnosis processes, therapeutics, and nutraceuticals are based on organic molecules. MILS-26 reviews in 7 comprehensive chapters, written by 20 experienced authors, the most recent metal-containing molecules and nanomaterials for diagnosis and therapy.Features: The field of metallodrugs has been flourishing and this area of research can be used to diagnose specific biologically relevant molecules or unravel cellular metabolism. The authors are preeminent bioinorganic and medicinal inorganic chemists and review the most current research in this field. The book discusses the properties and therapeutic applications of metals and metal-containing molecules including the use of electrochemical or optical signal for diagnosis of biologically relevant molecules. It endorses and stimulates research in the vibrant field of biological inorganic chemistry. It reviews the most current research supporting the relevance of metal-containing molecules and nanomaterials for diagnosis and therapy.

Metal-Dielectric Interfaces in Gigascale Electronics

by Toh-Ming Lu Ming He

Metal-dielectric interfaces are ubiquitous in modern electronics. As advanced gigascale electronic devices continue to shrink, the stability of these interfaces is becoming an increasingly important issue that has a profound impact on the operational reliability of these devices. In this book, the authors present the basic science underlying the thermal and electrical stability of metal-dielectric interfaces and its relationship to the operation of advanced interconnect systems in gigascale electronics. Interface phenomena, including chemical reactions between metals and dielectrics, metallic-atom diffusion, and ion drift, are discussed based on fundamental physical and chemical principles. Schematic diagrams are provided throughout the book to illustrate interface phenomena and the principles that govern them. Metal-Dielectric Interfaces in Gigascale Electronics provides a unifying approach to the diverse and sometimes contradictory test results that are reported in the literature on metal-dielectric interfaces. The goal is to provide readers with a clear account of the relationship between interface science and its applications in interconnect structures. The material presented here will also be of interest to those engaged in field-effect transistor and memristor device research, as well as university researchers and industrial scientists working in the areas of electronic materials processing, semiconductor manufacturing, memory chips, and IC design.

Metal-Halide Perovskite Semiconductors: From Physical Properties to Opto-electronic Devices and X-ray Sensors

by Krzysztof Kris Iniewski Wanyi Nie

This book will provide readers with a good overview of some of most recent advances in the field of technology for perovskite materials. There will be a good mixture of general chapters in both technology and applications in opto-electronics, Xray detection and emerging transistor structures. The book will have an in-depth review of the research topics from world-leading specialists in the field. The authors build connections between the materials’ physical properties to the main applications such as photovoltaics, LED, FETs and X-ray sensors. They also discuss the similarities and main differences when using perovskites for those devices.

Metal-Ion Hybrid Capacitors for Energy Storage: A Balancing Strategy Toward Energy-Power Density (SpringerBriefs in Energy)

by Satyajit Ratha Aneeya Kumar Samantara

Rapid growth in the research and development of clean energy storage techniques has yielded a significant number of electrochemically active compounds/materials possessing enormous potential to facilitate the fabrication of next generation devices such as the supercapacitor. This Brief describes recent progress in the field of metal-ion based hybrid electrical energy storage devices, with emphasis on the effect of different metal ions and other constituent components on the overall electrochemical performance of battery-supercapacitor hybrids (BSHs). Although significant efforts have been made to create an effective electrical energy storage system that would have the energy density of a battery and the power density of a supercapacitor, persistent challenges still lie in combining these two altogether different systems to form a cost-effective and safe storage device. Detailed comparisons of output performance and longevity (in terms of cyclic stability) are provided, including device fabrication cost and safety.Of the several proposed schematics/prototypes, hybrid supercapacitors, with both carbon-based EDLC electrode and pure faradic (battery type) electrode can work in tandem to yield high energy densities with little degradation in specific power. As a promising electric energy storage device, supercapacitors address several critical issues in various fields of applications from miniaturized electronic devices and wearable electronics to power hungry heavy automobiles. Depending on the electrode configuration and other controlling parameters, these BSHs can have contrasting performance statistics. Metal ion BSHs such as Li+, Na+, Mg+2, Zn+2 etc., acid-alkaline BSHs, and redox electrolyte based BSHs all represent recent approaches, with BSHs based on metal ions, particularly Lithium, of particular interest because of the extreme popularity of Li-ion based batteries. This book is written for a broad readership of graduate students and academic and industrial researchers who are concerned with the growth and development of sustainable energy systems where efficient and cost-effective storage is key.

Metal-Matrix Composites: Advances in Analysis, Measurement, and Observations (The Minerals, Metals & Materials Series)

by T. S. Srivatsan W. C. Harrigan Jr. Simona Hunyadi Murph

This collection brings together engineers, scientists, scholars, and entrepreneurs to present their novel and innovative contributions in the domain specific to metal-matrix composites and on aspects specific to modeling, analysis, measurements, and observations specific to microstructural advances. Topics include but are not limited to: · Metals and metal-matrix composites · Nano-metal based composites · Intermetallic-based composites Contributions in the above topics connect to applications in industry-relevant areas: automotive, energy applications, aerospace, failure analysis, biomedical and healthcare, and heavy equipment and machinery.

Metal-Matrix Composites: Advances in Processing, Characterization, Performance and Analysis (The Minerals, Metals & Materials Series)

by Pradeep K. Rohatgi T. S. Srivatsan Simona Hunyadi Murph

This collection brings together engineers, scientists, scholars, and entrepreneurs to present their novel and innovative contributions in the domain specific to metal-matrix composites and on aspects specific to processing, characterization, mechanical behavior, measurements, failure behavior, and kinetics governing microstructural influences on failure by fracture. Topics include but are not limited to: • Metals and metal-matrix composites • Nano-metal based composites • Intermetallic-based composites Contributions in the above topics connect to applications in industry-relevant areas: automotive; nuclear and clean energy; aerospace; failure analysis; biomedical and healthcare; and heavy equipment, machinery, and goods.

Metal-Organic Framework Nanocomposites: From Design to Application

by Anish Khan, Mohammad Jawaid, Abdullah Mohammed Ahmed Asiri, Wei Ni, and Mohammed Muzibur Rahman

Metal-Organic Framework Nanocomposites: From Design to Application assembles the latest advances in MOF nanocomposites, emphasizing their design, characterization, manufacturing, and application and offering a wide-ranging view of these materials with exceptional physical and chemical properties. FEATURES Discusses various types of MOF materials, such as polyaniline MOF nanocomposites, magnetic MOF nanocomposites, and carbon nanotube-based MOF nanocomposites Includes chapters on the usage of these materials in pollutant removal, electrochemical devices, photocatalysts, biomedical applications, and other applications Covers different aspects of composite fabrication from energy storage and catalysts, including preparation, design, and characterization techniques Emphasizes the latest technology in the field of manufacturing and design Aimed at researchers, academics, and advanced students in materials science and engineering, this book offers a comprehensive overview and analysis of these extraordinary materials.

Metal-Organic Frameworks (MOFs) as Catalysts

by Shikha Gulati

This book highlights the state-of-the-art research and discovery in the use of MOFs in catalysis, highlighting the scope to which these novel materials have been incorporated by the community. It provides an exceptional insight into the strategies for the synthesis and functionalization of MOFs, their use as CO2 and chemical warfare agents capture, their role in bio-catalysis and applications in photocatalysis, asymmetric catalysis, nano-catalysis, etc. This book will also emphasize the challenges with previous signs of progress and way for further research, details relating to the current pioneering technology, and future perspectives with a multidisciplinary approach. Furthermore, it presents up-to-date information on the economics, toxicity, and regulations related to these novel materials.

Metal-Organic Frameworks for Photonics Applications

by Banglin Chen Guodong Qian

The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.

Metal-Organic Frameworks in Biomedical and Environmental Field

by Patricia Horcajada Cortés Sara Rojas Macías

This book joins an international and interdisciplinary group of leading experts on the biomedical, energy and environmental applications of Metal-Organic Frameworks (MOFs). The resulting overview covers everything from the environmentally friendly and scale up synthesis of MOFs, their application in green energy generation and storage, and water purification to their use as drug delivery systems, biosensors, and their association with relevant macromolecules (genes, enzymes). This book is focused on the interest of MOFs in applications such as the leading –edge environmental (energy-related) and biomedical fields. The potential of MOFs in these areas is currently progressing at a fast pace, since the wide possibilities that MOFs offer in terms of composition, topology, incorporation of active species (in their porosity, on their external surface or within the framework), and post-synthetic modifications, among others. The aim here is to provide future research goals that emphasize relevant nuances to this class of materials as a whole.

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